Abstract

AbstractBased on the performance of improving the stabilities and coloring efficiencies of triphenylamine polymers, this paper separately synthesized different diamines and 3,4‐dimethylthieno[2,3‐b]thiophene‐2,5‐dicarboxylic acid, and the electrochromic functions of the polymer films were studied on indium‐tin oxide glass (ITO) glass. The polymers had a thiophene group, which was rich in π‐electrons and conducive to molecular stability, and showed good stabilities. Ultraviolet spectrum showed that all the six polymers had a wide absorption band in the neutral range of 200–700 nm. Electrochromic analysis showed that the six kinds of polymer films all showed reasonable optical contrast, short response time and low band gap in the infrared spectrum range of 200–1000 nm. Among them, the film formed by PAD2 on ITO glass had better electrochromic properties, longer bleaching response time (tc = 1.3 s, tb = 4.1 s), PAD3 had better coloration efficiency (214 cm2 C−1).

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.