Preparation and electrochemical studies of metal–carbon composite catalysts for small-scale electrosynthesis of H 2O 2

Abstract

Numerous transition metal–carbon composite catalysts (M = V, Zn, Ni, Sn, Ce, Ba, Fe, Cu) have been synthesized and tested for electroreduction of O 2 to H 2O 2, The activity and selectivity of all synthesized catalysts for electrosynthesis of H 2O 2 were determined by the rotating ring-disk electrode method in acidic and neutral electrolytes. The Co-based catalysts in general showed the highest activity towards H 2O 2 formation. Experiments with different loading contents of Co showed that the activation overpotential losses of oxygen reduction to H 2O 2 reduces as loading increases to about 4 wt% Co. Addition of Co beyond this level did not seem to impact the overpotential losses. The cobalt-based catalysts, were spray-coated onto 120 μm thick Toray ® graphite substrates, and were studied in bulk electrolysis cells for up to 100 h at potentiostatic conditions (0.25 V vs. RHE) in pH 0, 3, and 7 electrolytes. At (25 °C and 1 bar) with a catalysts loading of about 1 mg c m geometric − 2 and using dissolved O 2 in 0.5 M H 2SO 4, typical H 2O 2 electrosynthesis rates of about 5 μ mol h − 1 c m geometric − 2 were reached with current efficiencies of about 85 ± 5% at 0.25 V (vs. RHE).