Abstract
A new inorganic/organic composite film PEDOT:Ce@TiO2 was prepared through drop casting-secondary polymerization method using the mixture solution of PEDOT oligomer and cerium-containing polyoxotitanate cage [Ti8O7(HOEt)(OEt)21Ce]. PEDOT:Ce@TiO2 exhibits a special nanostructure with gully-like rough surface, which shows strong hydrophobicity while good wettability to acetonitrile solution. PEDOT:Ce@TiO2 can be used as cathodically electrochromic film and supercapacitor electrode material. The mass specific capacitance of PEDOT:Ce@TiO2 is 71.2 F/g at a current density of 1 A/g, which is 1.7 times higher than that of the PEDOT film. An all-solid-state electrochromic supercapacitor prototype device was further assembled using PEDOT:Ce@TiO2. With charging completed the electrochromic area of this device shows dark green, and it turns bright yellow with discharging completed.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
