Abstract
NASICON-type Li1+xAlxGe2-x(PO4)3 solid state lithium ionic conductors were synthesized by a sol-gel method using citric acid and ethylene glycol. The obtained precursors were sintered at various temperatures and the NASICON-type single phase was observed in a range of x = 0–0.6. The highest electrical conductivity was obtained for Li1.4Al0.4Ge1.6(PO4)3 sintered at 900°C for 11 h in air. The total conductivity was 1.22×10−3 S cm−1 at 25°C, and the bulk and grain boundary conductivities were estimated by impedance profile analysis to be 1.70×10−3 and 4.30×10−3 S cm−1, respectively. Sintered pellets of Li1.4Al0.4Ge1.6(PO4)3 were immersed in distilled water, saturated LiCl aqueous solution, and a saturated LiCl and LiOH aqueous solution at 50°C for one week; X-ray diffraction patterns of these samples dried at 220°C under vacuum showed no significant change from that of the pristine sample. The electrical conductivity of Li1.4Al0.4Ge1.6(PO4)3 was decreased to 1.4×10−4 S cm−1 at 25°C by immersion in distilled water, while immersion in the saturated LiCl aqueous solution increased the conductivity to 4.95×10−3 S cm−1 at 25°C. Li1.4Al0.4Ge1.6(PO4)3 was stable in the saturated LiCl and LiOH aqueous solution. Li1.4Al0.4Ge1.6(PO4)3 was unstable in contact with Li metal and Li-In alloy, but was stable in contact with Li7Ti5O12.
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