Preparation and Effect of Methyl-Oleate-Based Polyol on the Properties of Rigid Polyurethane Foams as Potential Thermal Insulation Material.

Abstract

Recently, most of the commercial polyols used in the production of rigid polyurethane foams (RPUFs) have been derived from petrochemicals. Therefore, the introduction of modified palm oil derivatives-based polyol as a renewable material into the formulation of RPUFs is the focus of this study. A palm oil derivative-namely, methyl oleate (MO)-was successfully modified through three steps of reactions: epoxidation reaction, ring-opened with glycerol, followed by amidation reaction to produce a bio-based polyol named alkanolamide polyol. Physicochemical properties of the alkanolamide polyol were analyzed. The hydroxyl value of alkanolamide polyol was 313 mg KOH/g, which is suitable for producing RPUFs. Therefore, RPUFs were produced by replacing petrochemical polyol with alkanolamide polyol. The effects of alkanolamide polyol on the physical, mechanical and thermal properties were evaluated. The results showed that the apparent density and compressive strength increased, and cell size decreased, upon introducing alkanolamide polyol. All the RPUFs exhibited low water absorption and excellent dimensional stability. The RPUFs made with increased amounts of alkanolamide polyol showed higher thermal conductivity. Nevertheless, the thermal conductivities of RPUFs made with alkanolamide polyol are still within the range for thermal insulating materials (<0.1 W/m.K). The thermal stability of RPUFs was improved with the addition of alkanolamide polyol into the system. Thus, the RPUFs made from alkanolamide polyol are potential candidates to be used as insulation for refrigerators or freezers.