Abstract

Cu+‐ion‐conducting glasses were prepared in the pseudoternary system CuBr–Cu2MoO4–Cu3PO4, and the ion‐conducting properties of the glasses obtained were compared to those of the glasses in the system CuI—Cu2MoO4—Cu3PO4, which contain CuI instead of CuBr. The CuBr—Cu2MoO4—Cu3PO4 glasses showed high ion conductivities in the range of 100 to 10−2 S · m−1 at room temperature. The change in ion‐conducting properties caused by the substitution of PO3‐4 anions for MoO2−4 anions was larger than the change caused by the substitution of Br− anions for I− anions in the glasses containing a constant amount of the cuprous halides.

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