Abstract
The synthesis of trans-[NiBr{C 6H 3-2,6-(CH 2PCy 2) 2}], Cy = cyclohexyl, and its characterisation by spectroscopy and single crystal X-ray analysis are described. The constraints imposed by the bulky terdentate ligand lead only to minor distortions of the square planar nickel(II) coordination (PNiP = 161.6(1)°). The nickel coordination is compared with those found in related complexes with terdentate N- and P-donor ligands.
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