Abstract

Complete solid solutions of Fe(Sb 1− x Te x ) 2 and Co(Sb 1− x Te x ) 2 with marcasite or pseudomarcasite structures have been synthesized. Lattice parameters a, b, and c follow Vegard's law in both series. From the results of crystallographic data, it is expected that the iron and cobalt ions change their apparent valence state from 4 to 2 due to anion replacement of Sb by Te.

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