Abstract
AbstractReaction of an alkyne‐bridged dicobalt complex, [Co2(CO)6(μ‐Me3SiC=Cpy)] 4, with bis(diphenylphosphino)methylene (DPPM) or bis(diphenylphosphino)ethylene (DPPE) in THF at 55 °C yielded a DPPM or DPPE doubly bridged dicobalt compound, [{μ‐P,P‐PPh2CH2PPh2}Co2(CO)4(μ‐Me3SiC=Cpy)] 5 or [{μ‐P,P‐PPh2CH2CH2PPh2}Co2(CO)4(μ‐Me3SiC≡Cpy)] 6. Compound 5 and 6 were characterized by spectroscopic means as well as X‐ray crystal structure determination.
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