Abstract
Abstract The effects of phase changes on the photocatalytic and catalytic activities of SnO2/TiO2 nanoparticles prepared via a surfactant-assisted sol-gel method were investigated. The as-prepared SnO2/TiO2 was calcined at 400°, 500°, 600°, and 700 °C. The prepared samples were studied by XRD, TEM, SEM, FTIR, BET, UV-vis diffuse reflection spectroscopy (DRS) and Photoluminescence (PL) spectra. The results showed that the crystallite size and anatase-to-rutile phase transformation increased greatly with increasing the calcination temperature. The transformation of anatase to rutile phase was found to be between 400° and 600 °C, and then the anatase completely transformed to rutile phase at 700 °C. Also, the specific surface area and pore volume decreased, whereas the mean pore size increased with increasing the calcination temperature. The effect of calcination temperature on the catalytic activity of the samples was tested by different applications: photodegradation of Methylene Blue (MB), Rhodamine B (RhB) dyes and phenol and synthesis of xanthene (14-phenyl-14H-dibenzo [a,j]xanthene). The mineralization of MB and RhB has been confirmed by chemical oxygen demand (COD) measurements. The SnO2/TiO2 nanoparticles calcined at 500 °C are found to exhibit the highest photocatalytic and catalytic activities.
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