Preparation and characterization of slow-release fertilizers loaded guar gum-g-poly methylmethacrylate-cl-polylactic acid (Gg-g-PMMA-cl-PLA) hydrogel and its effect on wheat growth

Abstract

In order to reduce the harmful effects of synthetic non-biodegradable hydrogel, biopolymers have attracted attention, particularly for use in slow-release fertilizers. The current attempt intends to develop a hydrogel from biopolymers for sustainable release of water and nutrients in soil. Here, guar gum is used as a polysaccharide, MMA as a monomer, KPS as an initiator, and Polylactic acid as a cross-linker. Further investigation is done to study synthesized hydrogel in the development of wheat crop. Biodegradation study shows that it's environmentally favorable and degradable, contributing nutrients to the soil as it decomposes. Fertilizer release studies in soil and water show that the timing of the nutrient release is delayed, improving soil water holding capacity and retention studies. The agronomic parameters show that fertilizers-loaded hydrogel has a positive effect on physiological, morphological characteristics like shoot length, root length, number of shoots and roots, shoot weight and root weight, chlorophyll content, and most notably, fruiting efficiency is enhanced as compared with commercially available hydrogel. ATR-FTIR, SEM-EDX, TGA-DTA, and XRD analysis used to confirm successful loading of fertilizers and biodegradation of hydrogel. The encouraging findings suggested that this hydrogel could be used as a multifunctional, fertilizers-loaded hydrogel in crop production.