Preparation and characterization of planar Ni–Au bimetallic model catalysts

Abstract

Ni–Au bimetallic model catalysts were prepared as thin films on Re(0001) or Ru(0001) single crystal substrates. Surface compositions and electronic structures of the Ni–Au thin films were characterized by low energy ion scattering spectroscopy and X-ray photoelectron spectroscopy, respectively. Surface alloys were prepared by annealing Ni–Au thin films from 500 to 800K, resulting in substantial surface enrichment of Au. Annealing a Ni–Au thin film with a 1:1 bulk composition ratio at 700K for 10min resulted in a surface alloy with 84% (atomic concentration) of Au in the outermost surface layer. The surface atomic structure was investigated using CO as probe molecules, which exclusively adsorbs on the Ni atoms rather than on the Au atoms at room temperature. Polarization modulation infrared reflection absorption spectroscopy of CO adsorption on Ni–Au surface alloys showed that CO adsorption on two-fold bridge sites decreased and finally disappeared with an increase of Au surface concentration. The absence of Ni bridge site CO adsorption indicated that Ni atoms were isolated by Au atoms on Ni–Au alloyed surface.