Preparation and characterization of phase change capsules containing waste cooking oil for asphalt binder thermoregulation

Abstract

The green utilization of waste is of great significance to the sustainable development of human society. In this work, a new kind of capsule with the phase change heat storage function was prepared using waxy components extracted from waste cooking oil (WCO) as core material for the thermoregulation of asphalt binder. The differences in waxy components before and after hydrolysis treatment were studied including functional groups, phase transition temperature, and phase transition enthalpy. Meanwhile, the surface morphology, thermodynamic properties, and mechanical properties of the phase change capsules (PCCs) were also characterized comprehensively. Additionally, the effect of PCCs on asphalt thermoregulation was also examined in the laboratory. The results indicate that the waxy components after hydrolysis treatment are more suitable for asphalt binder thermoregulation in terms of the phase transition temperature, phase transition enthalpy, and thermal stability. According to the results of differential scanning calorimeter and thermogravimetric experiments, it can be calculated that the ratio of wall material and core material in PCCs is about 1:1, which endows the capsule with excellent heat storage properties (125 J/g), mechanical properties (>13 N), and thermal stability (>190 ℃). With the help of the temperature sensor, it is found that PCCs can delay the change rate of asphalt temperature with the environment by undergoing a phase transition to mitigate the damage of asphalt pavement in extremely hot climates. However, the performance of PCCs in asphalt mixtures still needs to be further explored. Overall, the findings of this research can further promote the green utilization of WCO and the functionalization of construction and building materials.