Preparation and characterization of Pd/Al2O3 and Pd nanoparticles as standardized test material for chemical and biochemical studies of traffic related emissions

Abstract

Palladium model particles similar to those emitted from catalytic car exhaust converters were prepared and characterized with the intention of providing a standardized material for investigations of the chemical behavior and bioavailability of traffic related Pd emissions. Two series of Pd particles were prepared and characterized in detail: Pd nanoparticles (2–4 nm) dispersed on aluminum oxide particles of a diameter range between 0.1 to 30 μm and “Pd-only” nanoparticles of 5–10 nm in diameter. The Pd/α-Al2O3 particles are very similar to particles emitted from catalytic converters by mechanical abrasion. The Pd-only particles are useful e.g. for exposure studies in which the presence of aluminum could lead to interferences when studying biological and biochemical effects. The sample preparation procedure of both series was optimized in order to achieve elemental particles with proper sizes and a narrow size distribution. The obtained particles were characterized by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), selective area diffraction (SAD), laser granulometry and graphite furnace atomic absorption spectrometry (GFAAS) for the measurement of Pd concentrations.