Abstract
The electrochromic (EC) polyamides (Ether-PentiTPA1 and Ether-PentiTPA8) from the electroactive pentiptycene-derived triphenylaminediamine monomers (PentiTPA1 and PentiTPA8) were designed and prepared via polycondensation. The incorporation of rigid and contorted H-shaped pentiptycene scaffolds could restrain polymer chains from close packing and further form intrinsic microporosity in the polymer matrix which could be confirmed by the measurements of WXRD, BET, and PALS. With the existence of intrinsic microporosity, the diffusion rate of counterions between the electroactive polymer film and electrolyte can be promoted during the electrochemical procedure. Therefore, the prepared polyamide Ether-PentiTPA1 exhibits enhanced EC behaviors, such as lower driving potential (1.11 V), smaller redox potential difference ΔE (0.24 V), and shorter switching response time (3.6/5.2 s for coloring/bleaching). Consequently, the formation of intrinsic microporosity can be a useful approach for the enhancement of EC response performance.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
