Preparation and characterization of chitosan coatings onto regular cellulose fibers with ultrasound technique

Abstract

Regenerated cellulose fibers—viscose fibers—were coated with chitosan using an ultrasound technique to improve their accessibility, reactivity and sorption properties. The main purpose of our research was to study the modification of viscose fibers and to determine the effect of the application of chitosan onto viscose fibers. Samples were obtained by treating the fibers with chitosan in a dilute acetic acid solution in an ultrasonic bath. The influences of the chitosan coating on the changes in morphology, supramolecular structure, sorption and tensile properties were studied. The spectra (FTIR analysis) of the treated viscose fibers showed changes and new absorption bands that revealed the existence of the chemical interactions with the chitosan. The scanning electron microscope images confirmed that the surface of the fibers was covered with the chitosan. A decrease in the water retention value and increase in the absorption and moisture content with an increasing concentration of chitosan was noted. Furthermore, the differences in tensile behavior were analyzed using an Instron tensile testing machine. The chitosan coating had no effect on the tensile strength of the viscose fibers, but influenced the tensile strain. Some changes, though not significant, were noted in the structure (crystallinity, orientation) of the treated viscose fibers.