Preparation and characterization of cellulose-chitosan/β-FeOOH composite hydrogels for adsorption and photocatalytic degradation of methyl orange

Abstract

Biopolymer-based hydrogels have received great attention in wastewater treatment due to their excellent properties, e.g., high adsorption capacity, fast kinetics, reusability and ease of operation. In the present work, cellulose-chitosan/β-FeOOH composite hydrogels were prepared via co-dissolution and regeneration process as well as hydrothermal in situ synthesis of β-FeOOH. Effect of β-FeOOH loading on the properties of the composite hydrogels and the removal efficiency of methyl orange (MO) was investigated. Results showed that β-FeOOH was uniformly loaded onto the hydrogel framework, and the nanoporous structure of composite hydrogels could increase not only the effective contact area between β-FeOOH and the pollutants but also the active sites. Moreover, the increased β-FeOOH loading led to the enhanced MO removal rate under light conditions. When the loading time was extended from 6 h to 9 h, the MO removal rate increased by 21%, which can be mainly due to the photocatalytic degradation. In addition, MO removal rate reached 97.75% within 40 min under optimal conditions and attained 80.81% after five repetitions. The trapping experiment and EPR results indicated that the main active species were hydrogel radicals and holes. Consequently, this work provides an effective preparation approach for cellulose-chitosan/β-FeOOH composite hydrogel with high adsorption and photocatalytic degradation, which would hold great promise for wastewater treatment applications.