Preparation and characterization of carbon-encapsulated iron nanoparticles and their catalytic activity in the hydrogenation of levulinic acid

Abstract

This study describes the synthesis of carbon-encapsulated iron nanoparticles using an ultrasonic method and also investigates their catalytic activity. These nanoparticles have been prepared using ultrasonic irradiation followed by annealing at various temperatures. As the annealing temperature of as-prepared α-Fe2O3 nanoparticles increased, the sample transformed into γ-Fe2O3, Fe3O4, and Fe nanoparticles via the reduction process without requiring any additional reducing agents such as H2 gas, thus, creating a carbon shell surrounding the nanoparticles. By controlling the experimental conditions, Fe nanoparticles of various sizes can be formed with diameters in the range 100–800 nm; these nanoparticles are tightly encapsulated by 20-nm-thick carbon shells. Because of their high saturation magnetization 212 emu g−1, the carbon-encapsulated Fe nanoparticles can be used for magnetic resonance imaging with a dramatically enhanced efficiency compared to commercially available T2 contrast agents. Moreover, the carbon-encapsulated Fe nanoparticles showed its superior catalytic activity and reusability for the hydrogenation of biomass-derived levulinic acid to GVL (99.6 %) in liquid phase.