Preparation and characterization of carbon-coated LiFePO 4 cathode materials for lithium-ion batteries with resorcinol–formaldehyde polymer as carbon precursor

Abstract

LiFePO 4/C composites were synthesized by two methods using home-made amorphous nano-FePO 4 as the iron precursor and soluble starch, sucrose, citric acid, and resorcinol–formaldehyde (RF) polymer as four carbon precursors, respectively. The crystalline structures, morphologies, compositions, electrochemical performances of the prepared powders were investigated with XRD, TEM, Raman, and cyclic voltammogram method. The results showed that employing soluble starch and sucrose as the carbon precursors resulted in a deficient carbon coating on the surface of LiFePO 4 particle, but employing citric acid and RF polymer as the carbon precursors realized a uniform carbon coating on the surface of LiFePO 4 particle, and the corresponding thicknesses of the uniform carbon films are 2.5 nm and 4.5 nm, respectively. When RF polymer was used as the carbon precursor, the material showed the highest initial discharge capacity (138.4 mAh g − 1 at 0.2 C at room temperature) and the best rate performance among the four materials.