Abstract
It is a challenge to simultaneously achieve a high selectivity and permeance for the glassy polymeric membranes. Herein, the asymmetric Kapton membrane fabricated by pyromellitic dianhydride and 4,4′-oxydiphenylenediamine was prepared by the phase inversion method and characterized by rheometer, SEM, TGA, FT-IR and tensile testing. The aim of this work is to enhance gas separation performance of the membrane and its application value via optimizing the concentration of acetone additive, coagulation bath composition and evaporation time. After optimizing, results showed that the transition from the instantaneous coagulation to the delayed coagulation, and the inner membrane structure is gradually transferred from the finger-like shape to the sponge-like shape. The optimized gas separation performance of the resulting Kapton membrane has the permeance of 2.49 GPU and 1.10 GPU for H2 and CO2, respectively, as well as selectivity of 57.07 and 25.27 for H2/CH4 and CO2/CH4, respectively.
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