Abstract

AbstractThe poly(acrylonitrile‐co‐vinylidene chloride‐co‐divinylbenzene) beads with macroporous morphology were synthesized by suspension polymerization. The use of dichloroethane as a solvating diluent resulted in copolymer beads having highly porous structures. These have been reacted with hydroxylamine in methanol, which generates amidoxime groups. The precursory resins were readily functionalized within 0.5–1 h. A detailed analysis is made of the pore structure of resins in the anhydrous state including pore size distribution and specific surface area. © 1994 John Wiley & Sons, Inc.

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