Abstract

ABSTRACT Acrylic resins are known for their multifarious characteristics. Diversified properties of acrylic resins have been utilised for the development of acrylic cationic electrodeposition multicolour mono-coat corrosion protective coatings by acrylic graft polymer of methyl acrylate, butyl acrylate, styrene, and methyl methacrylate in the presence of hydroxy propyl acrylate at 113–117°C in the presence of AIBN (Azo-bis iso-butyronitrile) as the initiator. The concept was to develop acrylic graft polymer wherein chemical bonds are protected against UV radiation 400 h or 18-month outdoor exposure. Developed acrylic resin has special characteristic e.g. excellent metal protection against corrosion 500 h salt spray test as per ASTM B117, excellent durability, economical primer, and finish coat in single application and meeting the International and National legislation. Resulting polymers were characterised by using FTIR spectroscopy, particle size analyser and other Morden instrumental techniques. Thus the obtained polymers have high solid content (72 ± 1%) and can be used in electrodeposition emulsion paint as a binder. The coatings are mono-coat prepared and their anticorrosion behaviour is discussed in this paper. The experimental results depict that the resin thus synthesised has high anticorrosive property, UV light stability, and excellent weather resistance.

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