Abstract

The scale inhibitor was prepared based on itaconic acid (IA), styrene p-sulfonic sodium (SSS), maleic anhydride (MA), and acrylamide (AM) as monomers, and ammonium persulfate as an initiator by the free-radical polymerization. The structure of the polymer was characterized by FT-IR and UV-Vis spectroscopy. Using the static experiment method, the scale inhibition efficiency to CaCO3, the effects of some factors (concentration of polymer, time, concentration of Ca2+, pH value, concentration of HCO3 −, and temperature) were investigated. Using the malachite green photometric method, the scale inhibition efficiency to Ca3(PO4)2 and the effects of some factors (concentration of polymer, time, Ca2+, pH, temperature, and the concentration of PO4 3−) were also investigated. The experimental results showed that the polymer had an excellent efficiency of scale inhibition and a resistance rate of calcium carbonate scale up to 96.67%, a resistance rate of calcium phosphate scale up to 92.5%, and could be used in the system of high-temperature and high-hardness water. The polymer had good dispersing ability with respect to iron.

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