Abstract
The ZSM-5 zeolite is widely used to catalyze the reactions of methanol to olefins. Herein, we have prepared the H-ZSM-5 doped with barium (Ba/ZSM-5) using incipient wetness impregnation method. The Ba modified catalysts were used to catalyze a new reaction of methanol with methyl vinyl ether to improve the selectivity of ethylene and propylene (C2=+C3=). The reaction catalyzed by Ba doped H-ZSM-5 shows higher propylene selectivity over H-ZSM-5. The reaction mechanism is discussed.
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