Abstract
Expanding the application area of photovoltaics to urban environments demands high efficiency under low-intensity lighting conditions, as well as omnidirectional light trapping. Dye-sensitized solar cells are of particular interest in this regard, owing to their superior electricity production in dim light; however, an improvement in dye-sensitized solar cells efficiency is required for successful implementation. We developed a light-trapping layer within the photoanode of dye-sensitized solar cells and configured these cells into an angled three-dimensional (3D) array creating a submodule to improve efficiency. The light-trapping layer increases the travel distance of the light within the photoanode, thus improving electron generation by the photons of the omnidirectional incident light. The 3D angled array suppresses recombination and internal resistance losses, improving the collection efficiency by increasing the relative cell surface area with respect to the light projection area. Using the proposed configuration, we achieved a dye-sensitized solar cells submodule efficiency of 8.5% using 5%-efficient dye-sensitized solar cells with a pot-shaped light-trapping layer and a 60° angled 3D array for the submodule. Considering that there is room for further improvement, our proposed photovoltaics configuration is expected to overcome the current limitations of dye-sensitized solar cells, thus providing promising photovoltaics modules for urban environments.
Highlights
Photovoltaic (PV) application is expected to continue its expansion into urban life[1,2,3]
Dye-sensitized solar cells (DSSCs) have a low-light absorption coefficient compared with other types of thin-film solar cells, requiring a thick photoanode for optimal photon absorption
We suggest that additional investigation into the design of the lighttrapping layer is needed to further improve the effective charge generation within the DSSC photoanode, such that the light absorption coefficient of a DSSC approaches that of a direct band gap-structured thin-film solar cell
Summary
Photovoltaic (PV) application is expected to continue its expansion into urban life[1,2,3]. A well-designed light-trapping layer enhances the charge generation within the photoanode by modifying the light path, i.e., increasing the light travel length (or effective light absorption coefficient).
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