Preliminary trace element analysis of arsenic in Nepalese groundwater may pinpoint its origin

Abstract

Arsenic contamination of groundwater used as drinking water in South Asia poses a serious health threat to the inhabitants living on alluvial plains of the Himalayan foreland of countries like Bangladesh, India, Nepal and Myanmar. Although the geological and geochemical conditions favoring the release of the highly poisonous contaminant from the sediments hosting the groundwater are meanwhile quite well understood, there is still a significant debate about the origin of arsenic. The sediments forming a huge proportion of the Terai (lowlands of Nepal) aquifers are derived from two main sources, (i) sediments deposited by large rivers that erode the upper Himalayan crystalline rocks and (ii) weathered meta-sediments carried by smaller rivers originating in the Siwalik foothills adjacent to the Terai. In this article a so far underestimated source of As is discussed: the peraluminous leucogranites found ubiquitously in the Nepal Himalaya. The relationship between the trace elements analyzed in the groundwater in the Terai and trace elements found in such felsic rocks reflect the origin of the arsenic in the high Himalayas of Nepal. In addition to the high concentration of As, a striking feature is the presence of the lithophile trace elements like Li, B, P, Mn, Br, Sr and U in the groundwater. The mentioned elements point to a felsic initial source like metapelites or leucogranites—all rocks showing a high abundance of especially B, P and As as well as Cd and Pb.