Abstract
Persistent organic pollutants (POPs) have been measured using passive air samplers (PASs) over two years (2017–2018) in the city of Tunis within the framework of the UNEP/GEF GMP2 projects to support Stockholm Convention implementation. Several POPs, although banned for a long time from Tunisia, were registered in relatively high amounts in the atmospheric compartment. The most unexpected compound is hexachlorobenzene (HCB), with concentrations ranging from 5.2 ng/PUF to 16 ng/PUF. Furthermore, the current results seem to confirm the presence of dichlorodiphenyltrichloroethane (DDT) and its transformation products and hexachlorocyclohexanes (HCHs) at relatively high concentrations (4.6 ng/PUF to 9.4 ng/PUF and 2.7 ng/PUF to 5.1 ng/PUF, respectively), followed by hexabromocyclododecane (HCBD), which varies from 1.5 ng/PUF to 7.7 ng/PUF. Nondioxin-like PCB (ndl-PCB) concentrations in Tunis were very high (62.0 ng/PUF to 419.3 ng/PUF), higher than those in other African countries participating in this project. Uncontrolled combustion seems to be one of the most important sources of the emanation of dioxin compounds dl-PCBs and Polychlorinated dibenzodioxins PCDD/polychlorinated dibenzofurans PCDF. Toxic equivalents (TEQs) ranged from 4.1 pg WHO-TEQ/PUF to 6.4 pg WHO-TEQ/PUF. The perfluorinated compounds (PFAS) and congeners of polybrominated diphenyl ethers (PBDEs) show relatively low amounts that remain below the African continent average. The PFAS pattern suggests a local source rather than long-range transport. These results constitute the first exhaustive work capable of providing an overview of the levels of POPs in the air in Tunis. As a result, it will be possible to set up an adequate monitoring program with specific investigations and experimental studies.
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