Abstract

In the late 19th and early 20th centuries, original photographs were sent to publishers so that they could be reproduced in print. The photographs often needed to be reworked with overpainting and masking, and such modifications were especially necessary for low-contrast photographs to be reproduced as a letterpress halftone. As altered objects, many of these marked-up photographs were simply discarded after use. An album at The New York Public Library, however, contains 157 such photographs, all relating to the Jackson–Harmsworth expedition to Franz Josef Land, from 1894 to 1897. Received as gifts from publishers, the photographs are heavily retouched with overpainting and masking, as well as drawn and collaged elements. The intense level of overpainting on many of the photographs, but not on others, raised questions about their production and alteration. Jackson’s accounts attested to his practice of developing and printing photographs on site, testing different materials and techniques—including platino-bromide and silver-gelatin papers—to overcome the harsh environmental conditions. In this context, sixteen photographs from the album were analyzed through a combination of non-invasive and micro-invasive techniques, including X-ray fluorescence (XRF) spectroscopy, fiber optics reflectance spectroscopy (FORS), Raman and Fourier-transform infrared (FTIR) spectroscopies, and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM/EDS). This analytical campaign aimed to evaluate the possible residual presence of silver halides in any of the preliminary and improved photographs. The detection of these compounds would be one of several factors supporting a hypothesis that some of the photographs in the album were indeed printed on site, in the Arctic, and, as a result, may have been impacted by the extreme environment. Additional goals of the study included the evaluation of the extent of retouching, providing a full characterization of the pigments and dyes used in overpainted prints, and comparing the results with contemporaneous photographic publications that indicate which coloring materials were available at the time. Further analyses shed light on the organic components present in the binders and photographic emulsions. This research has increased our knowledge of photographic processes undertaken in a hostile environment such as the Arctic, and shed light on the technical aspects of photographically illustrating books during the late 19th and early 20th centuries.

Highlights

  • Mid-19th-century polar expeditions relied on photography to record and document their journeys and the landscape of the far North

  • The present study focused on a selection of sixteen photographs, all documenting the Jackson-Harmsworth expedition to Franz Josef Land between 1894 and 1897, contained in an album titled Arctic Exploration in the Photography Collection of the NYPL

  • Visual examination of the photographs combined with scientific analysis by means of an array of non-invasive and micro-invasive spectroscopic techniques sought to determine whether any of these photographs may have been printed on site, during the expedition in the Arctic, as well as to investigate the photographic process and materials used for retouching improved positives

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Summary

Introduction

Mid-19th-century polar expeditions relied on photography to record and document their journeys and the landscape of the far North. The NYPL’s Arctic Exploration album was subjected to an in-depth analytical campaign aiming to evaluate the possible presence of residual silver halides in any of the preliminary and improved photographs The detection of these compounds would be one of several factors supporting a hypothesis that some of the photographs in the album were printed on site, in the Arctic, and, as a result, may have been impacted by the extreme environment. A limited number of microscopic paint samples was removed from retouched areas of photographs 18, 31, 48, and 56 (Table 1) using a surgical scalpel blade These samples were analyzed by micro-Raman and Fourier-transform infrared (FTIR) spectroscopies, as well as scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM/EDS), to identify pigments and dyes in more detail, and to investigate the organic components present in the binders and photographic emulsions. Improved (retouching) S2) Scraping of purple-blue paint from sky on top edge at proper left of center

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Conclusions
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