Preliminary evaluation of a natural surfactant extracted from Myrtus communis plant for enhancing oil recovery from carbonate oil reservoirs

Abstract

Surfactants are among the materials used to improve water properties for injection into oil reservoirs, and reduce injection phase and crude oil interfacial tension (IFT). Recently, the interest in the use of natural surfactants has increased and is constantly on the rise to solve some challenges of using chemical surfactants such as incompatibility with the environment and the high cost. In this study, we have used aqueous extract of powdered leaf of Myrtus communis as an available source of natural surfactant. The extracted surfactant was characterized by TGA, 1H NMR and FTIR techniques. The surfactant efficiency was demonstrated by performing some experiments including IFT and injection of chemical slug and surfactant into carbonate plugs. The surfactant adsorption on carbonate rock was also studied. It was observed that this natural surfactant can reduce IFT to 0.861 mN/m at surfactant critical micelle concentration (CMC) of 5000 ppm. This minimum IFT was further reduced at optimum salinity and alkali. Finally, an increase of 14.3% oil recovery by surfactant flooding and 16.4% oil recovery by ASP slug injection containing NaOH alkali and partially hydrolyzed polyacrylamide (PHPA) polymer with 0.5 PV volume from carbonate plugs was achieved.