Preindustrial levels and temporal enrichment trends of mercury in sediment cores from the Gulf of Thailand.

Abstract

Four sediment cores in the middle of Gulf of Thailand (GOT) and one core close to Bang Pakong River mouth were examined for total mercury (T-Hg) using direct thermal decomposition coupled with the atomic absorption spectrometry (DTD-AAS) method and acid digestion (acid-CVAAS) method, and sediment chronologies using 210Pb dating. T-Hg in the river mouth core ranged 44.49-52.76µg/kg and higher than the cores from the middle of GOT (18.26-36.68µg/kg). The age span obtained from the cores dated back to the 1940s with the sediment accumulation rates of 0.15-0.76cm/year. The preindustrial levels of T-Hg showed an initial slow increase followed by a rapid elevation since the 1960s which marked the start of the industrialized period in the country. To this end, we posit that T-Hg in the GOT sediment can be attributed to not only land-based sources but also offshore activities including petroleum exploration and frequent accidental oil spills.