Abstract
Abstract In contrast to cis-4-hydroxy-2-tetralincarboxylates, cis-4-hydroxy-2-chromancarboxylates take diaxial conformation having 4-pseudoaxial-OH and 2-axial-COOR groups preferably. The preferred conformations of these compounds were rationalized by molecular force field (MM 1/MMP 1) calculations on the corresponding 2-tetralin- and 2-chromancarbaldehydes as model compounds.
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