Abstract
In this study, a phase-switching process is introduced to a PM6:Y6-based active layer to implement a uniform surface with preferred Y6 acceptor-domain positioning and to minimize solution loss owing to the use of medium molds. By designing the process to fit the surface properties of a small-molecule Y6 acceptor-based bulk heterojunction, a sustainable and highly reproducible phase-switched active layer that can be formed at the desired location without wasting materials is successfully formed over an area of 2.25 cm2. It improved charge transport ability and suppressed surface defects owing to a molecular orientation favorable for efficient charge separation and transport. Furthermore, adding chloronaphthalene induced the domain growth of Y6 acceptors with dense molecular packing, which enhanced the effects of the phase-switching process. Uniformly distributed performance in the phase-switched active layer via the phase-switching process was demonstrated in fabricated large active-area devices. Furthermore, the process was utilized in a PM6:Y6-based self-powered photodetector, which improved detectivity owing to the suppression of the dark current density. Therefore, the phase-switching process is an important technology for forming high-quality thin films composed of small-molecule acceptors for efficient self-powered photodetector and photovoltaic applications.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
