Abstract
The preferential solvation in binary mixtures containing methanol, ethanol, acetone or triethylamine and another organic solvent has been examined by means of the quasi-lattice quasi-chemical (QLQC) and inverse Kirkwood–Buff integrals (IKBI) methods. The results are expressed in terms of the composition of the environment close to a given molecule in the mixtures, and are rationalized in terms of the interactions that take place in them.
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