Abstract

AbstractThe preferential adsorption of dilute solutions of poly(methyl methacrylate) and some poly(alkyl methacrylate)s in 1,4‐dioxane/methanol, at 298 K, was studied by laser light scattering. It was found that the inversion composition depends on the molar volume or the number of carbon atoms of the polymer side group. This result can be explained in terms of specific interactions between the carbonyl group of the esters and methanol.

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