Abstract
AbstractWe describe a bis‐N‐heterocyclic carbene rhodium(III) complex, featuring two trifluoroacetato ligands, that affords a variety of α‐vinylsilanes in good yields by hydrosilylation of terminal alkynes. Selectivities around 7:1 α/β‐(E) were reached, while the β‐(Z) product was only marginally obtained. This example sharply contrasts with the β‐(Z)‐selectivity observed for its parent diiodido complexmagnified image
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