Preference of curing regimes based on fire resistance of ultra-high performance cementitious materials (UHPCM) mixed with fly ash

Abstract

The cement-fly ash (FA) binary system was prepared as the ultra-high performance cementitious materials (UHPCM), and the effect of curing regimes on the evolution of microstructure and compressive strength of UHPCM at elevated temperatures was investigated. The results showed that multi-stage combined curing (MC) could remarkably improve the compressive strength of UHPCM at ambient temperature, which attributed to the further hydration of cement and the pozzolanic reaction of FA to produce more stable hydrates. However, steam curing (90 °C for 7 d) was more conducive to the residual compressive strength growth and retention of UHPCM exposed to elevated temperatures. The mechanism of this phenomenon was revealed by XRD and SEM analysis. The further hydration and conversion reactions occurred mainly inside the steam cured specimens when exposed to fire temperature, and a large number of C–S–H gels were gradually transformed into crystalline hydrates with high strength, excellent thermal stability and different forms, which made the microstructure denser and thus had better fire resistance. Comparatively, a large number of crystalline hydrates were generated prematurely in dry-hot air cured specimens, which made the decomposition reactions dominate under fire, resulting in coarsening of microstructure and reduction of macroscopic mechanical strength of UHPCM continuously.