Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials

Abstract

The description and prediction of the thermophysical and transport properties of ternary organic non-electrolyte systems including water by the polynomial equations are reviewed. Empirical equations of Radojkovic et al. (also known as Redlich-Kister), Kohler, Jacob-Fitzner, Colinet, Tsao-Smith, Toop, Scatchard et al. and Rastogi et al. are compared with experimental data of available papers appeared in well know international journals (Fluid Phase Equilibria, Journal of Chemical and Engineering Data, Journal of Chemical Thermodynamics, Journal of Solution Chemistry, Journal of the Serbian Chemical Society, The Canadian Journal of Chemical Engineering, Journal of Molecular Liquids, Thermochimica Acta, etc.). The applicability of empirical models to estimate excess molar volumes, VE, excess viscosities, ?E, excess free energies of activation of a viscous flow,