Abstract
Abstract The octanol/water partition coefficients (POW) were predicted for five vanadium(IV)–porphyrin complexes which were taken as model compounds of petroporphyrin. The correlation between the reversed-phase liquid chromatographic retention factor and the POW observed for standards was applied to the prediction. The log POW values estimated for the metalloporphyrins range from 5.8 (for 5,10,15,20-tetramethylporphine complex) to 10.1 (for 2,3,7,8,12,13,17,18-octaethylporphine complex).
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