Abstract

A measuring technique suitable for the prediction of the electroanalytical equilibrium signal of a potentiometric sensor is described, based on the evaluation of asymptotes of the response of the cell and the confidence interval from the signals measured in the so-called information dominant section of the response. The equilibrium voltage can be evaluated with the great precision by comparing the calculated data with a predetermined threshold value. The technique was applied to the determination of the equilibrium signal of a carbon dioxide sensor.

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