Abstract
Quantum chemical calculations including embedding, scalar relativistic, and dynamic electron correlation effects on Cs(2)NaYCl(6):(CeCl(6))(3-) embedded clusters predict (i) redshifts of the f(1)-->d(t(2g))(1) transition with pressure and (ii) bond-length shortening upon f-->d(t(2g)) excitation. Both effects are found to be connected which suggests that new high-pressure spectroscopic experiments could reveal the sign of the bond-length change.
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