Abstract
For natural plant raw materials and for artificial mixture samples with different lignin content, a comparison between empirical equations for the calculation of higher heating values was carried out relying on the data of ultimate analysis. Selection of tested equations from already known was carried out according to the criteria: equations should be intended for work with plant raw materials; the range of used materials should be rather wide; the data on element content (C, H, N, S) obtained experimentally and in routine mode, as well as ash value of the material, should be variables; ambiguous equations should be excluded. Only 8 from more than 150 published equations were chosen for testing, and 3 of these provide calculation of higher heating values with a less than 5–6% deviation from reference values obtained by means of combustion in an adiabatic calorimeter.
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