Prediction of component activities in the ternary molten slags containing titanium oxide by pseudo-multicomponent approach of MIVM

Abstract

Based on the molecular interaction volume model (MIVM) and the coexistence theory model (CTM), the component activities were predicted in the ternary slags FeO-MnO-SiO2, FeO-MnO-TiO2, MnO-SiO2-TiO2 and FeO-SiO2-TiO2. In com parison with the experiment data, the total average relative errors of the predicted value by pseudo-multicomponent approach of MIVM were 16%, the total average standard deviations were 0.062. On the other hand, the total average relative errors of the predicted value by coexistence theory model were 28%, the total average standard deviations were 0.077. The predicted effect of the pseudo-multicomponent approach of MIVM has better stability and reliability than coexistence theory. Therefore, the activities of component TiO2 were predicted in the ternary slags FeO-MnO-TiO2, MnO-SiO2-TiO2 and FeO-SiO2-TiO2 by MIVM, the corresponding isoactivity curves were plotted and the thermodynamic behavior tendency of constituent TiO2 in different slag systems was analyzed. This work has enriched the thermodynamic data of titanium-containing slag system and made up for the deficiency of high temperature experiment to some extent.