Predicting the removal efficiency of pharmaceutical and personal care products using heated metal oxides as adsorbents based on their physicochemical characteristics

Abstract

Pharmaceutical and personal care products (PPCPs) are emerging pollutants that are commonly found in the environment and exist predominantly in nondegradable forms. Several attempts have been made to remove PPCPs via conventional wastewater treatment processes; however, these processes have limitations, such as high costs and insufficient removal efficiencies. Adsorption is a promising alternative for removing PPCPs because it is inexpensive, highly reusable, and easy to operate. Therefore, this study aims to determine the contributing characteristics that can be used to predict the adsorption behaviour of PPCPs based on their physicochemical properties, with heated metal oxide adsorbents (HMOAs). HAOP (heated aluminium oxide particles) and HIOP (heated iron oxide particles) with particle sizes below 38 μm were used. Results from the Brunauer-Emmett-Teller (BET) analysis show that HIOP has higher surface area and smaller pore size (113.7 ± 26.3 m2/g and 5.4 ± 1.8 nm) than HAOP (14.5 ± 0.6 m2/g and 18.6 ± 3.1 nm), which suggest that HIOP would show superior adsorption rates compared to HAOP. The adsorption mechanism is identified based on three major physicochemical properties of PPCPs: molecular weight (M.W.), octanol–water partition coefficient (log Kow), and acid dissociation constant (pKa). The results suggest that the most dominant factor that contributes to the adsorption of PPCPs on to HMOAs is the M.W., where the larger the molecular size, the better the adsorption efficiency. The tests conducted with varying log Kow values revealed that the hydrophilicity of the adsorbent influences the adsorption performance. It was found that HIOP exhibits better removal efficiencies with hydrophilic PPCPs (up to 83%) than with hydrophobic PPCPs (48%), while HAOP exhibits better removal efficiencies with hydrophobic PPCPs (86%) than with hydrophilic PPCPs, with less than 10% removal. Unlike the M.W. and pKa values, the log Kow does not exhibit any visible trend. Therefore, the adsorption behaviour can be predicted with the M.W. and pKa values of the PPCPs, when HAOP and HIOP are used as adsorbents.