Predicting the Heat Generation Rate in Large Format Pouch-Type Lithium-Ion Battery Cells for Automotive Applications

Abstract

Accurate prediction of the heat generation rate of lithium ion batteries is critical for driving towards a cost effective and efficient design of a thermal management system for various applications.[1, 2] because of the increase in battery cell dimensions associated with an increase in battery cell capacity to drive towards a reduction in range anxiety for automotive applications, as well as more aggressive operating conditions that are typically seen in the automotive industry, such as direct current fast charge and sustained driving under load, heat generation at the cell level must be considered as spatially nonuniform during operation. Proper design of the thermal management system requires prediction[3] of the heat generation of the battery cell in both a lumped fashion for system sizing, as well as a distributed mode in order to focus cooling appropriately to decrease local temperature extremes. Local temperature extremes can adversely affect the aging of the battery cell due to the non-uniformities in electrochemical utilization of the active material, increased local reaction rates, and increased mechanical stresses in active materials.In this work, we detail our efforts to characterize the heat generation[4] of a battery cell under a variety of operating conditions, quantify the impact of temperature non-uniformities[5] on the aging of the battery cell, and experimentally[6, 7] evaluate the localized aging in the battery electrodes based on local temperature conditions. Here, we will describe the modeling methods developed to link operating conditions, aging, and heat generation with the electrochemical performance of the battery cell. A discussion of the model performance for relevant automotive applications will also be included.References M. Song, Y. Hu, S.-Y. Choe and T. R. Garrick, J Electrochem Soc, 167, 120503 (2020).Y. Hu, S.-Y. Choe and T. R. Garrick, Electrochim Acta, 362, 137124 (2020).M. Song, Y. Hu, S.-Y. Choe and T. R. Garrick, J Electrochem Soc, 169, 070502 (2022).Y. Hu, S.-Y. Choe and T. R. Garrick, Applied Thermal Engineering, 189, 116709 (2021).Y. Hu, S.-Y. Choe and T. R. Garrick, J Power Sources, 532, 231350 (2022).U. Janakiraman, T. R. Garrick and M. E. Fortier, J Electrochem Soc, 167, 160552 (2020).T. R. Garrick, J. Gao, X. Yang and B. J. Koch, J Electrochem Soc, 168, 010530 (2021).