Abstract

An empirical model is proposed to predict the energy position of the metal-to-metal charge transfer (MMCT) bands in closed shell d 0 transition metal complex oxides doped with Bi 3+ or Pb 2+ ions. The model is constructed on the basis of optical data compiled from the literature and from the investigation of the luminescence properties of a series of compounds (titanates, vanadates, niobates, tantalates, molybdates, and zirconates) prepared and characterized in this work.

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