Abstract

A comparison is performed between the multiple parallel and two-competing reaction models in their ability to predict high-temperature (above 1000°K) lignite devolatilization data. The multiple parallel reaction model was subsequently seen to be the better fit of this high-temperature data. Finally, this multiple parallel reaction scheme was shown to adequately model lignite devolatilization data at temperatures from 973 to 2100°K, residence times from 0.001 to 10.0 sec. and heating rates from 180 to 1,000,000°K/s.

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