Abstract
The chemical system of monomolecular reactions among n species, first analysed in the classical paper by Wei and Prater (1962) was revisited. It was shown that using symmetry relationships, based on all the equilibrium constants and n(n−1)/2 known dependences, all remaining kinetic dependences can be calculated. A new method of closing the mass balance for such a complex chemical system was developed, using only measurements of one or a few species, and based on symmetry relations. A new method of testing completeness of a kinetic description was proposed, using the properties of the trace sum of components, i.e., the sum of all concentration dependences, each of which is started from maximal initial concentration.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
