Abstract
The synthesis of alloy nanocatalysts with controllable sizes and shapes is a critical prerequisite for vapor–liquid–solid (VLS) growth of one-dimensional nanostructures. In this work, we comprehensively examined surface reactions between evaporated In atoms and a Bi thin film on a Si(111) surface at ambient temperature. InBi2 liquid nanodroplets nucleate and grow during initial vapor–solid (VS) reaction between the In vapor and surface Bi atoms, and the reaction proceeds until a saturation point is reached, following which InBi2 begins to catalyze subsequent VLS growth of various nanocrystals under persistent In-beam flux. The scaled size distribution of individual InBi2 nanodroplets could be explained adequately using the classical capillary nucleation theory, which suggests that the simultaneous homogeneous nucleation of InBi2 nanodroplets occurs during the vapor–solid (VS) reaction of In and Bi.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.