Abstract
AbstractRaman scattering, X‐ray, microprobe, and electron microscopy experiments show that precipitates of the crystallographic phase 6NaCl · CdCl2 are present in NaCl crystals doped with CdCl2 in the concentration range from 0.008 to 2.2 mol%. The size of the precipitates increases with increasing Cd concentration. If the NaCl: Cd crystals are quenched in a few seconds from 550 to 20 °C the main Raman peak is shifted to higher frequencies. This shift of the Raman peak is interpreted as being caused by the smaller size of the precipitates in quenched crystals.
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