Abstract

Abstract The reactions of N-(cyclohexylthio)phthalimide (CTP), in the absence of zinc oxide, leading to the inhibition of vulcanization in a N-t-butyl-2-benzothiazole sulfenamide (TBBS) accelerated sulfur cure were studied in the presence and absence of rubber. Mixtures of CTP, TBBS and sulfur were heated in a DSC and the reaction products and residual curatives analyzed by HPLC. Cyclohexanethiol, a decomposition product of CTP, reacted with TBBS producing 2-mercaptobenzothiazole (MBT) and t-butylamine, both of which reacted with CTP. In a polyisoprene compound, the addition of CTP did not delay the formation of the initial crosslinks, however the crosslink density did not increase substantially until the CTP had been consumed. MBT, a product of the crosslinking reaction, reacted preferentially with the CTP and not the TBBS. In the absence of CTP, the MBT was shown to accelerate the rate of TBBS polysulfide formation leading to a rapid rise in crosslink density.

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